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Application of selective 13C{1H} nuclear overhauser effects with low-power 1H irradiation in carbon-13 NMR spectroscopy

✍ Scribed by Jun Uzawa; Setsuo Takeuchi

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
335 KB
Volume
11
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The feasibility of the application of selective ^13^C{^1^H} nuclear Overhauser effect (NOE) measurements to organic structural analysis in ^13^C NMR spectroscopy has been investigated at 25 MHz using citraconic anhydride and the methyl ester of pentalenolactone as model compounds. This selective ^13^C{^1^H} NOE technique with single frequency low‐power ^1^H irradiation should find wide application in the structural elucidation of organic compounds, especially for the reliable assignment of quaternary carbon signals.

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