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Application of Ruthenium Complexes of Triazole-Containing Tridentate Ligands to Asymmetric Transfer Hydrogenation of Ketones

โœ Scribed by Johnson, Tarn C.; Totty, William G.; Wills, Martin

Book ID
115533988
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
353 KB
Volume
14
Category
Article
ISSN
1523-7060

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Highly effective NPN-type tridentate lig
Highly effective NPN-type tridentate ligands for asymmetric transfer hydrogenation of ketones
โœ Yutong Jiang; Qiongzhong Jiang; Guoxin Zhu; Xumu Zhang ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 195 KB

New chiral NPN-type tridentate ligands containing two oxazoline rings and one phosphine have been synthesized, and their Ru(II) complexes show high reactivity and enantioselectivity in transfer hydrogenations of both aryl alkyl and dialkyl ketones (with ee's up to 92% for a dialkyl ketone).