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Application of RCM Reaction in the Construction of ABC Ring of Micrandilactone A

✍ Scribed by Zhang, Yan-Dong; Tang, Ye-Feng; Luo, Tuo-Ping; Shen, Juan; Chen, Ji-Hua; Yang, Zhen

Book ID: 127372472
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 119 KB
Volume: 8
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol052630h

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## Abstract **Throw your hat in the ring**: A highly diastereoselective synthesis of the ABC rings of (−)‐norzoanthamine has been achieved starting from the (−)‐Hajos–Parrish ketone (see scheme). Three asymmetric quaternary carbon centers on the C ring were constructed by a 1,4‐addition, and an int