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Application of rank correlation to lanthanide induced shift data

✍ Scribed by Wai-Kee Li; Sik-Yum Lee

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
254 KB
Volume
13
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Spearman's rank correlation method is suggested as an alternative procedure for the treatment of lanthanide induced shift data. When this method is applied to Sullivan's data [J. Am. Chem. Soc. 98, 7162 (1976)], the results are similar to those obtained by the jack‐knife and Kendall techniques, which were introduced in a previous article. All three methods are able to distinguish between closely related structures. Among these three non‐parametric methods, the Spearman procedure is probably the simplest.

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