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Application of palladacycle catalyst in the synthesis of mono-arylpyridyl bromides

✍ Scribed by Jinli Zhang; Yangjie Wu; ZhiWu Zhu; Gerui Ren; Thomas C. W. Mak; Maoping Song


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
134 KB
Volume
21
Category
Article
ISSN
0268-2605

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Synthesis of a Chiral Palladacycle and I
✍ Yi Ding; Yi Zhang; Yongxin Li; Sumod A. Pullarkat; Paul Andrews; Pak-Hing Leung 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 465 KB 👁 2 views

## Abstract A novel amine ligand, 1‐(2,5‐dimethylphenyl)‐__N__,__N__,2,2‐tetramethylpropan‐1‐amine, was synthesized in six steps from commercially available __p__‐xylene. Direct __ortho__‐palladation of this amine ligand proceeded readily to form the racemic dimeric complex. The palladacycle struct