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Application of P-chirogenic bisphospholane ligands to rhodium catalyzed asymmetric hydrogenation of α- and β-acetamido dehydroamino acid derivatives

✍ Scribed by Garrett Hoge; Brian Samas


Book ID
108283773
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
246 KB
Volume
15
Category
Article
ISSN
0957-4166

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The applications of the chiral dipyridylphosphine ligand P-Phos and its derivatives Tol-P-Phos and Xyl-P-Phos in Ruand Rh-catalyzed hydrogenations of the methyl esters of a variety of (Z)-2-acetamido-3-arylacrylic acids have been studied systematically. The results show that the electronic and steri