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Application of oxidative aryl migration in organo-selenium and -tellurium compounds to the synthesis of 2-arylpropanoic acids

โœ Scribed by Uemura, Sakae; Fukuzawa, Shin-ichi; Yamauchi, Takayoshi; Hattori, Kaneaki; Mizutaki, Shoichi; Tamaki, Kentaro


Book ID
119973649
Publisher
Royal Society of Chemistry
Year
1986
Weight
626 KB
Category
Article
ISSN
1472-7781

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Ring-Opening Reactions of 3-Aryl-1-benzy
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Nucleophilic ring-opening reactions of 3-aryl-1-benzylaziridine-2-carboxylates were examined by using O-nucleophiles and aromatic C-nucleophiles. The stereospecificity was found to depend on substrates and conditions used. Configuration inversion at C(3) was observed with O-nucleophiles as a major r