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Application of non-equilibrium thermodynamics to surfactant diffusion

✍ Scribed by Nabil Mikati


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
442 KB
Volume
123
Category
Article
ISSN
0009-2614

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✦ Synopsis


Surfactant diffusion is studied using non-equilibrium thermodynamics. Equations for the phenomenological coefficients, the main diffusion coefficient of the surfactant component and the cross diffusion coefficients are derived. The estimated D values of the surfactant component agree reasonably well with the experimental data provided that the concentrations are not too high. At zero salt the decrease and sudden increase in D near the CMC is predicted. The equations obtained for the cross phenomenological coefficients of the neutral components satisfy Onsager's reciprocal relations.


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