Application of methylation analysis in the determination of the structure of disaccharides containing 2,3-diamino-2,3-dideoxy-d-glucose (GlcN3N) associated with the backbone of lipid A
✍ Scribed by Anthony P. Moran; Dieter Scholz; Ulrich Zähringer
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 482 KB
- Volume
- 231
- Category
- Article
- ISSN
- 0008-6215
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Two new glycosyl amino acids N'~-Fmoc-Ser[Ac4-fl-D-Galp-(1 ~ 3)-Ac2-a-D-GalN3P]-OPf p and N'~-Fmoc-Thr[Ac4-/3-D-Galp-(1 ~ 3)-Ac2-a-D-GalN3p]-OPf p were synthesized. Glycosylation of N'~-Fmoc-Ser-OPf p or N ~-Fmoc-Thr-OPfp with protected/3-o-Gal-( 1 -~ 3)-D-GaIN 3 donors afforded the glycosyl amino a
## Abstract Two neutral complexes [(L~6~^3^4M)Fe~2~Cl~4~]·2H~2~O·2CHCl~3~ (1) and [(L~6~^3^4M)Mn~2~Cl~4~]·CH~3~CN (2) have been synthesized {L~6~^3^4M = __N__,__N__,__N′__,__N′__‐tetrakis[(6‐methyl‐2‐pyridyl)methyl]propane‐1,3‐diamine} and their molecular structures established by X‐ray crystallogr