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Application of mass spectrometry to the study of fluoropolymers. II. The copolymer from trifluoronitrosomethane (CF3NO) and tetrafluoroethylene (C2F4)

✍ Scribed by Flowers, W. T. ;Haszeldine, R. N. ;Henderson, E. ;Lee, A. K. ;Sedgwick, R. D.

Publisher: Wiley (John Wiley & Sons)
Year: 1972
Tongue: English
Weight: 335 KB
Volume: 10
Category: Article
ISSN: 0449-296X
DOI: 10.1002/pol.1972.170101204

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✦ Synopsis

Abstract

The techniques of mass spectrometry have been applied to the copolymer from tri‐fluoronitrosomethane (CF~3~NO) and tetrafluoroethylene (C~2~F~4~). The copolymer yields spectra of a repetitive nature, typical of the repeating units in the polymer chain. Molecules with masses up to m/e 6400 can be distilled from the unfractionated polymer which is stable up to 220°C. Interpretation of the mass spectrum suggests a linear structure for the regular polymer.

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