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Application of many-body perturbation methods in a discrete orbital basis

✍ Scribed by M.A. Robb

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
379 KB
Volume
20
Category
Article
ISSN
0009-2614

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✦ Synopsis

The many-body perturbation theory techniques used by Kelly to cslcuiate "pair correhtion energies" have been implemented in a discrete orbital basis using a set of coupled non-linear equations. The methodology differs from the usual "independent pair" methods in that the pairs arc coupled by "rearrangement" effects. Some numcriwl results on B-H are given to illustrate the utility of the method.

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