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Application of mannich reaction to sulfones I. Reactive methylene moiety of sulfones

✍ Scribed by W. Lewis Nobles; B. Blackburn Thompson

Book ID
102397298
Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
471 KB
Volume
54
Category
Article
ISSN
0022-3549

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Conjugate-addition reactions of highly-f
Conjugate-addition reactions of highly-functionalized aryl lithium reagents to Ξ³-silyloxy-Ξ±,Ξ²-unsaturated sulfones: consequences of the structure of the sulfone moiety.
✍ D.L. Barton; P.C. Conrad; P.L. Fuchs πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 224 KB

The effect of sulfone structure (phenyl vs t-butyl) is compared in the conjugateaddition reactions of ortho substituted and ortho, ortho disubstituted aryl lithium reagents -with y-silyloxy-a,@-unsaturated sulfones. Our earlier reports on the use of y-oxido-a,B-unsaturated sulfones (& n=5,6,7