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Application of free rotational models of molecular reorientation to the explanation of high frequency effects in dielectric relaxation

✍ Scribed by Coffey, W. T.; Déjardin, P. M.; Walsh, M. E.

Book ID
120002873
Publisher
American Institute of Physics
Year
1999
Tongue
English
Weight
438 KB
Volume
110
Category
Article
ISSN
0021-9606

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Application of the model-free approach to low molecular weight systems with hindered internal rotation: cinnamoylmesitylene
✍ Pavletta S. Denkova; Valentin S. Dimitrov; Snezhana M. Bakalova; Jose Kaneti; Kr 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 153 KB

## Abstract We investigated the molecular dynamics of the molecule of cinnamoylmesitylene, a substituted chalcone. Known rotation barriers for the OC‐4—C‐3C‐2 bond of substituted chalcones are in the range of values accessible to modern NMR techniques. The internal rotation about the C‐3—C‐4 bond