## Photoacoustic Fourier transform infrared (PA-FT-i.r.) spectrometry was employed to examine raw coal containing 1344 wt%, daf volatile matter (VM). Sample preparation for i.r. examination was the same as for ASTM proximate analysis. Technological and spectroscopic information on representative s
Application of Fourier-transform infrared spectroscopy to the characterization of fractionated coal liquids
โ Scribed by Paul C. Painter; Michael M. Coleman
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 1014 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0016-2361
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โฆ Synopsis
Fourier-transform infrared spectroscopy offers considerable advantages over conventional dispersive methods for the characterization of highly absorbing materials such as coal. This technique has been applied to the determination of the functional groups present in three solvent-refined-coal samples, all of which were obtained from the same parent coal but under different processing conditions. Both the benzene-soluble and pyridine-soluble portions are subjected to chromatographic fractionation by sequential elution from a silica-gel column using a specific sequence of solvents. The functional groups present in each fraction were identified from their infrared spectrum, using the groupfrequency approach.
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