Application of extended Hückel theory to x-ray photoelectron spectra of transition metal complexes. Correlations between electron binding energy and calculated atomic charge in iron and sulphur compounds

✍ Scribed by L.N. Kramer; M.P. Klein

• Publisher: Elsevier Science
• Year: 1971
• Tongue: English
• Weight: 489 KB
• Volume: 8
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(71)80009-x

✦ Synopsis

Comparisons of iron and sulphur atomic charges, derived fram extended Hiickeef calcutntions, with core electron binding energies determined from X-rap photoelectron spectrostopy yield good correlations Car neutral molecules. The assumptions and limitations of such correlations are discussed briefly.