## Abstract Styrene was polymerized using different amounts of azoisobutyronitrile as initiator at temperatures of 70Β°C, 75Β°C and 80Β°C in suspension. The course of reaction up to almost complete conversion was modeled within a classical kinetic framework. Optimal simultaneous descriptions of both c
Application of ESR spectroscopy to the kinetics of free radical polymerization of methyl methacrylate in bulk to high conversion
β Scribed by R. Wayne Garrett; David J. T. Hill; James H. O'Donnell; Peter J. Pomery; Catherine L. Winzor
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 264 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0170-0839
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π SIMILAR VOLUMES
The effect of fullerene (C 60 ) on the radical polymerization of methyl methacrylate (MMA) in benzene was studied kinetically and by means of ESR, where dimethyl 2,2Π-azobis(isobutyrate) (MAIB) was used as initiator. The polymerization rate (R p ) and the molecular weight of resulting poly(MMA) decr
## Abstract Previously obtained experimental conversionβdependences of the propagation rate coefficient (__k__~p~), the termination rate coefficient (__k__~t~) and the initiator efficiency (__f__) for the freeβradical bulk polymerization of styrene at 70βΒ°C have been used to simulate the full molec