Kinetics of oxidation of thiocyanate ion (NCS-) by iodine monochloride and iodine has been studied in aqueous perchloric acid medium. The rates of oxidations followed the rate laws: Variations in ionic strength and dielectric constant of the medium had little effects on the rates of reactions with
Application of electrometric technique in the kinetic study of iodination of cinnamaldehyde and furfuraldehyde with hydrated monopositive iodine
β Scribed by J.R. Yadav; K.L. Yadava
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 257 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0013-4686
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Complex formation in the ternary system of amylose (degree of polymerization, DP, 1100), SDS, and iodine was studied statically by spectrophotometry and amperometric titration and kinetically by the pressure-jump method. It was clarified that (1) iodine (Is) to some extent binds to amylose saturated
The gas phase reaction I, + HCOOCH, +HI + CH,I + CO, has been studied spectrophotometrically in a static system over the pressure ranges I, (6-39 torr) and HCOOMe (28-360 torr). In the temperature range 293-356', the initial rate of disappearance of I, is first order in [HCOOMe] and half-order in [I