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Application of chiral (E)-crotylsilanes in synthesis: The asymmetric synthesis of the C1C17 polypropionate fragment of rutamycin B

✍ Scribed by Nareshkumar F. Jain; James S. Panek

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
234 KB
Volume
38
Category
Article
ISSN
0040-4039

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Application of chiral (E)-crotylsilanes
Application of chiral (E)-crotylsilanes in synthesis: The asymmetric synthesis of the C19C34 spiroketal fragment of rutamycin B
✍ Nareshkumar F. Jain; James S. Panek 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 218 KB

The asymmetric synthesis of the spiroketal fragment of mtamycin B is reported employing allylsilane bond construction methodology for the introduction of five of the eight stereogenic centers. In this paper, the construction of the CI9-C28 and C29-C34 fragments as well as their coupling through an a