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Application of cerium(IV)/EDTA complex for future biotechnology

✍ Scribed by Jun Sumaoka; Wen Chen; Yoshihito Kitamura; Takafumi Tomita; Junya Yoshida; Makoto Komiyama


Book ID
116598827
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
224 KB
Volume
408-412
Category
Article
ISSN
0925-8388

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## Abstract A prerequisite for the high activity of the FeO^2+^ moiety as a hydroxylation agent is that its ligand environment stabilizes the 3Οƒ\*↑LUMO, which dominates the reactivity of this system. Features in the ligand environment that promote the reactivity of FeO^2+^ are: weak equatorial liga