Application of benzothiazoles to carbon-carbon bond formation in organic synthesis

✍ Scribed by E.J. Corey; Dale L. Boger

• Book ID: 104240292
• Publisher: Elsevier Science
• Year: 1978
• Tongue: French
• Weight: 287 KB
• Volume: 19
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)88968-1

✦ Synopsis

In the foregoing paper1 we described efficient routes to a variety of 2-vinyl benzothiazoles (vinyl BT's) and also mild, effective modification of C-2 of the BT nucleus to form carbonyl compounds. This note is primarily concerned with new carbon-carbon bond forming reactions of BT's which are highly effective for the stereoselective attachment of one or two carbon appendages to a ring and which substantially broaden synthetic methodology, I. VINYL BT's AS MICHAEL ACCEPTORS. An extensive and useful series of annulation processes could