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Application of an analytical modification of the iodolactonization reaction to selective detection of Δ5 (Δ4) unsaturated fatty acids

✍ Scribed by A.B. Imbs; D.V. Kuklev; A.D. Vereshchagin; N.A. Latyshev


Book ID
103041624
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
434 KB
Volume
60
Category
Article
ISSN
0009-3084

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Methyl oleate is converted in high yield to methyl 9(10)-methoxystearate by reaction with methanol in the presence of mercuric acetate followed by demercuration with sodium borohydride. Similar ethoxy-, hydroxy-, acetoxy-, acetylamino-, and hydroxyethoxystearates result when the nucleophilic solvent