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Application of a thermal rearrangement reaction to questions of structure of condensed dihydrodiazepinones: The reaction of 2,3-diaminopyridine with ethyl benzoylacetate

✍ Scribed by Mervyn Israel; Lynne C. Jones


Book ID
112122001
Publisher
Journal of Heterocyclic Chemistry
Year
1969
Tongue
English
Weight
332 KB
Volume
6
Category
Article
ISSN
0022-152X

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## Abstract Condensation of 3‐nitro‐1,2‐phenylenediamine with ethyl acetoacetate in boiling xylene gave two isomeric 2,3‐dihydro‐4‐methyl‐9‐nitro‐ and 2,5‐dihydro‐4‐methyl‐6‐nitro‐1__H__‐1,5‐benzodiazepin‐2‐ones, the 9‐nitro derivative thermal rearrangement product __N__‐isopropenyl‐4‐nitrobenzimid