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Application of a new nucleophilic addition/ring closure (NARC) sequence to the synthesis of enantiomerically-pure 2,8-dioxabicyclo[3.2.1]octanes of relevance to the squalestatins and zaragozic acids

✍ Scribed by Gary D. Fallon; Eric D. Jones; Patrick Perlmutter; Walailak Selajarern

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 227 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01523-3

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✦ Synopsis

A rapid method for the enantioselective construction of 2,8-dioxabicyclo[3.2.1]octanes of relevance to the zaragozic acids, employing a tandem NARC sequence of aldol and intramolecular Wacker reactions, is described.

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