Application of a Catalytic Palladium Biaryl Synthesis Reaction, via C—H Functionalization, to the Total Synthesis of Amaryllidaceae Alkaloids.
✍ Scribed by Jose C. Torres; Angelo C. Pinto; Simon J. Garden
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 32 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Application of a Stereospecific Intramolecular Allenylsilane Imino Ene Reaction to Enantioselective Total Synthesis of the 5,11-Methanomorphanthridine Class of Amaryllidaceae Alkaloids. -Starting from the enantiomerically pure epoxy alcohol (I) the allenylsilane aldehyde (II) is prepared. Its