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Application of 19F NMR spectroscopy to the study of equilibrium dynamics of uranyl(2+)-fluoride complexes

✍ Scribed by ZoltáN Szabó; Julius Glaser

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
664 KB
Volume
33
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

One‐ and two‐dimensional magnetization‐transfer ^19^F NMR methods were applied in a quantitative study of the fluoride exchange for uranyl(2+)‐fluoride complexes in aqueous solution. The applicability of these techniques and the classical lineshape analysis is discussed, and the quality of the results (rate constants and relaxation rates) obtained by the three methods is compared.

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