## Abstract A full discussion of the configuration of tricyclo [7.1.1.0^2,7^]undecanes related to __cis__β10, 10βdimethyltricyclo [7.1.1.0^2,7^]undecβ2βenβ4βone **(2)**, the __Robinson__ annelation product from norpinone **1** and 3βbutenβ2βone is given, based on 360βMHzβNMR. spectra. Nuclear __Ove
β¦ LIBER β¦
Apparent Failure of the Wharton Rearrangement in a Tricyclo[7.1.1.02,7]undecane
β Scribed by Alan F. Thomas; Roberto Di Giorgio; Olivier Guntern
- Book ID
- 102254452
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- German
- Weight
- 463 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
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The acid cataZysed rearrangement of to 2a is shown to proceed through concommitant eLectrophiZic and nucleophilic -attack on an alkene by an incipient carbonium ion and the remaining aZcoho2 function.