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Apparent and partial molar heat capacities and volumes of the amino acids l -lysine monohydrochloride andl -arginine monohydrochloride in aqueous solution at temperatures from T =  288.15 K to T =  328.15 K

✍ Scribed by Andrew W. Hakin; Gavin R. Hedwig


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
213 KB
Volume
33
Category
Article
ISSN
0021-9614

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✦ Synopsis


Relative densities and massic heat capacities have been determined for the amino acids L-lysine monohydrochloride and L-arginine monohydrochloride in aqueous solution at the temperatures T = (288. 15, 298.15, 313.15, and 328.15) K. These data have been used to calculate apparent molar properties which, in turn, were analyzed using extended Debye-HΓΌckel equations to yield partial molar heat capacities C ∞ p,m,Ο† and partial molar volumes V ∞ m,Ο† at infinite dilution. The partial molar properties have been used to calculate amino acid side-chain contributions which have been compared to those values previously reported in the literature.


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