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Apical and equatorial methoxy ligands on sulfuranes: effect on rates of pyridine methylation

✍ Scribed by Ohkata, Katsuo; Ohnishi, Masako; Yoshinaga, Keiichi; Akiba, Kinya; Rongione, Joseph C.; Martin, J. C.


Book ID
126097517
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
897 KB
Volume
113
Category
Article
ISSN
0002-7863

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A detailed conformational analysis was performed on the chair forms of piperidine, N-methylpiperidine, and some methylated derivatives Ž . using Hartree᎐Fock HF and MP2 ab initio methods with several basis sets Ž . from 3᎐21G to 6᎐311qqG\*\* , and the most widely used semiempirical Ž . approaches MN