The Influence of the Axial Ligands of a
β
Ellis, LT; Er, HM; Hambley, TW
π
Article
π
1995
π
Commonwealth Scientific and Industrial Research Or
π
English
β 612 KB
The electrochemical reduction and DNA binding have been studied for a series of platinum(IV) complexes with Cl-, OH-, and carboxylate anions as the axial ligands ; [Pt(en)Cl4], [Pt(en)Cl2(OH)2], and [Pt(en)Cl2(OC(O)R)2], R = CH3, CH2CH3, CH2CH2CH3. Cathodic reduction potentials vary by more than 650