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Antisymmetric exchange in the trinuclear clusters of copper (II)

✍ Scribed by B. S. Tsukerblat; B. Ya. Kuyavskaya; M. I. Belinskii; A. V. Ablov; V. M. Novotortsev; V. T. Kalinnikov

Book ID
104818745
Publisher
Springer
Year
1975
Tongue
English
Weight
405 KB
Volume
38
Category
Article
ISSN
1432-2234

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## Abstract The reactions of Cu^II^ carboxylates (valerate, 2‐methylbutyrate, hexanoate, heptanoate) with pyrazole (Hpz) in EtOH or EtOH/water solutions easily afford the triangular trinuclear copper derivatives [Cu~3~(ΞΌ~3~‐OH)(μ‐pz)~3~(RCOO)~2~(L)__~x~__] [R = CH~3~(CH~2~)~3~, L = H~2~O, __x__ = 1