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Antiresonances in the Rydberg spectrum of naphthalene. A new analysis

โœ Scribed by Donald Florida; Richard Scheps; Stuart A. Rice

Book ID
103013339
Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
312 KB
Volume
15
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The Rydberg "antiresonances" in the spectra of large molecules are reexamined under the assumption that Rydberg level-valence vibronic level mixing is of primary importance in determining the interference phenomenon. The line shape calculated using this point of view fits very well the observed "antiresonance" line shape in the naphthalene spectrum. The formalism also provides a satisfying rationalization for the absence of antiresonances in the Rydberg spectra of most large molecules.

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