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Antiparallel Pleated β-Sheets Observed in Crystal Structures of N,N-Bis(trichloroacetyl) and N,N-Bis(m-bromobenzoyl) Gramicidin S

✍ Scribed by Mitsunobu Doi; Saori Fujita; Yoshio Katsuya; Masahiro Sasaki; Taizo Taniguchi; Hiroshi Hasegawa


Book ID
115568963
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
328 KB
Volume
395
Category
Article
ISSN
0003-9861

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Conformational change from antiparallel
✍ Hiroyuki Oku; Keiichi Yamada; Ryoichi Katakai 📂 Article 📅 2008 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 510 KB

## Abstract The depsipeptides Boc‐Leu‐Lac‐OEt (1) and Boc‐(Leu‐Leu‐Lac)~__n__~‐OEt (__n__ = 1, 2) (**2** and **3**, respectively) (Boc = __tert__‐butyloxycarbonyl, Lac = L‐lactic acid residue) has been synthesized and studied by crystallographic, CD spectroscopic, and ESI‐MS analyses. In the packin