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Anti -Selective Direct Catalytic Asymmetric Aldol Reaction of Thiolactams

โœ Scribed by Sureshkumar, Devarajulu; Kawato, Yuji; Iwata, Mitsutaka; Kumagai, Naoya; Shibasaki, Masakatsu

Book ID
119942240
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
703 KB
Volume
14
Category
Article
ISSN
1523-7060

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โœ Yoshikawa, Naoki; Yamada, Yoichi M. A.; Das, Jagattaran; Sasai, Hiroaki; Shibasa ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 439 KB

The direct catalytic asymmetric aldol reaction using aldehydes and unmodified ketones is described for the first time herein. This reaction was first found to be promoted by 20 mol % of anhydrous (R)-LLB (L ) lanthanum, L ) lithium, B ) (R)-binaphthol moiety) at -20 ยฐC, giving a variety of aldol pro