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Anti-Kishi selective dihydroxylation of allylic alcohol derivatives

โœ Scribed by Oili A. Kallatsa; Ari M.P. Koskinen

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
197 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A highly diastereoselective dihydroxylation protocol has been developed for acyclic allylic alcohol derivatives leading to triol derivatives with diastereoselectivity reversed to the classical osmylation (anti-Kishi). Selectivities ate acceptable for E-allylic derivatives 1, and high for those derived from Z-derivatives 4.

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