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Anthraquinone sulphonate as a general-purpose shift reagent for the NMR analysis of cyclodextrins

✍ Scribed by Florence Djedaïni; Bruno Perly


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
267 KB
Volume
28
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The potential use of sodium anthraquinone 2‐sulphonate (ASANA) as a general‐purpose shift reagent for cyclodextrins is reported. It is demonstrated that completely resolved proton NMR spectra are obtained on inclusion of the host in the cavity of β‐and y‐cyclodextrins. The inclusion complexes have been characterized in terms of stoichiometry and association constants.