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Anthracyclinon-Ring-C-Synthese via Chelat-Carbenkomplexe

✍ Scribed by Prof. Dr. Karl Heinz Dötz; Dr. Michael Popall


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
203 KB
Volume
99
Category
Article
ISSN
0044-8249

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Anthracyclinone Ring C Synthesis via Che
✍ Prof. Dr. Karl Heinz Dötz; Dr. Michael Popall 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 335 KB 👁 2 views

The generation of I and their reactions with acid chlorides were performed in one flask as typified in the following example (reaction 3 in Table I). A mixture of Zn-Cu couple [I71 ( I 10 mg, 1.7 mmol) and 3-iodopropyl phenyl ketone (356 mg, 1.3 mmol) in dry benzene (4 mL) and HMPA (0.5 mL) was stir