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Anthracyclines and related substances I. A new friedel-crafts alkylation reaction using 3-bromophthalides. Efficient synthesis of islandicin.

✍ Scribed by K.S. Kim; M.W. Spatz; Francis Johnson


Book ID
104237534
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
214 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis


The synthesis of anthraquinones i and its higher homologs is generally accomplished by the two-step double acylation of aromatic substrates with phthalic anhydrides under Friedel-Crafts conditions (Scheme I). However the method has two drawbacks. It lacks

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This work and some of the results reported in this paper were presented at the