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Anomeric effect in hydrogen abstraction reactions of conformationally fixed 2-alkoxytetrahydropyrans

✍ Scribed by McKelvey, Ronald D.; Iwamura, Hiizu


Book ID
126298358
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
449 KB
Volume
50
Category
Article
ISSN
0022-3263

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Protonation and Hydrogen Atom Abstractio
✍ Scott Charles; Janet A. Danis; Sundeep P. Mattamana; James C. Fettinger; Bryan W πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 German βš– 122 KB

Ethylenediamine (en) solutions of [P 7 M(CO) 3 ] 3Β± (M = Cr, W) react with weak acids to give [HP 7 M(CO) 3 ] 2Β± ions where M = Cr (4 a) and W (4 b) in high yields. Competition studies with known acids revealed a pK a range for 4 b in DMSO of 17.9 to 22.6. The [P 7 M(CO) 3 ] 3Β± complexes also react