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Anomeric effect in 2-alkoxytetrahydropyrans studied by carbon-13 and oxygen-17 NMR chemical shifts

✍ Scribed by McKelvey, Ronald D.; Kawada, Yuzo; Sugawara, Tadashi; Iwamura, Hiizu


Book ID
126882568
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
601 KB
Volume
46
Category
Article
ISSN
0022-3263

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The 13 C chemical shifts of the title compounds (1) were determined in CDCl 3 and in CD 3 OD as well as in D 2 SO 4 solutions. Moreover 17 O chemical shifts of 1 in CDCl 3 were measured. The SCS (substituent-induced chemical shift) values were analyzed by means of linear free energy (LFE) relationsh