✦ LIBER ✦
Anomalously Coupled Nucleosides, II. Reaction of 3-[N6-(4-Chlorophenyl)-2-methyl-9-adenyl]-2,3-dideoxy-D-threo-pentopyranose with Alcohols and Anilines
✍ Scribed by Andersen, Jesper ;Pedersen, Erik B.
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 393 KB
- Volume
- 1987
- Category
- Article
- ISSN
- 0947-3440
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✦ Synopsis
3-
[ N"-(4-C hlorp henyt)-l-met hyl-9-adenyl]-2.3-dideoxy-~-lbreopcntopyranosc (1) has been converted into the alkyl 3-[P-(4clila rop henyl)-2-me thyI-9-adenyl]-2,3-dideoxy-o-rhreo-pento~yraiiosides 2 and into thc N-aryl-3-~N6~4-chlorophenyl)-2-methyl-~)-adc:nyl]-2.3-dideoxy-~-fhreo-pcntopyranosylamines 4. Thc compounds 2 wcre isolated as mixtures of CL and p anorners whcreas pure u momers 3 could be ohiained after prolonged reaction I II11L'S.