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Anomalous substituent effects observed for lanthanide-induced-shifts in substituted pyridines

✍ Scribed by G. Beech; R.J. Morgan

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
181 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

Lanthanide shift reagents have been widely applied' to structural studies of molecules with one or more donor atoms.

In these studies it is usual to assume that a donor atom lies along a principal magnetic axis of the lanthanide complex.

If this is so, the McConnell equation 2. is applicable so long as contact contributions (as opposed to pseudo contact) are negligible.

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