Anomalous reaction of adenine and 4-(hydroxymethyl)benzenediazonium ion
✍ Scribed by Peter M Gannett; Terence Lawson; Bela Toth
- Book ID
- 104227471
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 183 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
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2-Amino-4-methyloxazole gives 5-substituted products when treated with aldehydes instead of expected Schiff bases. Reactions of aldehydes and amines, including heterocyclic amines, are generally straight forward and give the expected imines or Schiff bases1'2'3. However, when an equimolar ratio of 2
## Abstract Reactions of 2,4,6‐trimethylbenzenediazonium (**1**), 2,6‐diethylbenzenediazonium (**2**) and 2,6‐diisopropylbenzenediazonium (**3**) tetrafluoroborates were studied in magic acid, SbF~5~/SO~2~ClF, acetonitrile and acetone by ^1^H‐NMR and by analysis of the dediazoniation products. The