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Anomalous Products from Intramolecular C−H Insertion by a Rhodium Carbenoid. Possible Involvement of a Zwitterionic Mechanism

✍ Scribed by White, James D.; Hrnciar, Peter


Book ID
118266509
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
95 KB
Volume
64
Category
Article
ISSN
0022-3263

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✍ J.Stephen Clark; Yung-Sing Wong; Robert J Townsend 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 81 KB

The mechanism of the anomalous intramolecular insertion reaction of a rhodium carbenoid into an ethereal C-H bond has been explored using deuterium labelled substrates. Comparison of primary kinetic isotope effects and analysis of ratios of diastereoisomeric deuterated products suggests the reaction