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Anomalous polarization: evidence for vibronic coupling in the allyl radical

✍ Scribed by James D. Getty; Xianming Liu; Peter B. Kelly

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 465 KB
Volume: 201
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85062-s

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✦ Synopsis

The resonance Raman spectra of the ally1 radical display intensity in the fundamental of non-totally symmetric modes. Mcasurement of the depolarization ratio on the vg and viz vibrational modes yields anomalous depolarization values. The anomalous depolarization ratios provide evidence for vibronic coupling of the ally1 radical-excited states in terms of B-term scattering.

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