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Anomalous magnetic properties of some TCNQ salts: alkali—crown ether—TCNQ ternary systems

✍ Scribed by Kikujiro Ishii; Hideyuki Nakayama; Fumiharu Abe


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
307 KB
Volume
91
Category
Article
ISSN
0009-2614

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✦ Synopsis


Optical and magnctlc properties arc reported for three TCNQ salts. N+cryptand[2,2,21 -TCNQ, Na-(dlbcnzo-IEcrownd)-TCNQand I<-(dibcnzo-IE-crowns)-TCNQ Elcctromc and vlbr31mnaI spectra tndlccrtc lbc weakness of the charge-transfer Interaction, whllc ESR and mvgnetlc susccpublhty suggest strong spm mteracuons III these s&.. A new rype of spin interaction between TCNQuuons is involved.