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Anomalous intensities and vibrational structure in the absorption spectra of benzene and benzene-d6

โœ Scribed by Gad Fischer; Alan E.W. Knight


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
979 KB
Volume
168
Category
Article
ISSN
0301-0104

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Spin-orbit relaxation of I(S2Pl/z)(aE = 0.94 eV) by benzene and benzende, has been studted at 297 K, using timeresolved atomic resonancefLuorescence. A large isotope effect is observed, IcC~H~ = (4.6 + 0.7) X lo-l3 cm3 molecule-' s-t, and ~C,D, = (9.9 c 1.0) X lo-l5 cm3 molecule-' s-l, despite evide