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Anomalous Fluorescence from the Azaxanthone Ketyl Radical in the Excited State

โœ Scribed by Sakamoto, Masanori; Cai, Xichen; Hara, Michihiro; Tojo, Sachiko; Fujitsuka, Mamoru; Majima, Tetsuro

Book ID
126153686
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
65 KB
Volume
127
Category
Article
ISSN
0002-7863

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The diphenyl ketyl radical which is formed upon photolysis of a-phenyl benzoin is produced in its excited state upon intense pulsed laser irradiation. Using the techniques of time-resolved absorption and emission spectroscopy, reaction rate constants for the ground and excited states of this radical