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Anomalous features of NH vibrational frequencies in complexes of zinc(II) with substituted anilines

✍ Scribed by L.S. Du Plessis; N.P. Slabbert; D.A. Thornton

Publisher: Elsevier Science
Year: 1967
Tongue: English
Weight: 255 KB
Volume: 1
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(67)80027-7

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✦ Synopsis

There is recent evidence which suggests that, even where a formal metal-lirand T-bonding concept cannot be invoked. electron withdrawing groups in amines mey stabilize complr:xes of these ligands. It is shown rhat infrared methods may be used to obtain evidence of anomalous s'abiliries in the N-H b0r.d: in zinc(n) complexes of anilines with mildly electron withdrawing substituentr,.

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