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Anomalous elimination of HCl from 2-chloro-1,1-difluoroethane. Likely involvement of a 1,2-FCl interchange mechanism

✍ Scribed by William R. Dolbier Jr.; Raphaele Romelaer; J.Marshall Baker


Book ID
104252174
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
103 KB
Volume
43
Category
Article
ISSN
0040-4039

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A kinetic study of the thermal eliminati
✍ J. A. Kerr; D. M. Timlin πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 619 KB

The kinetics of the thermal elimination of H F from 1,2-difluoroethane CHzFCHzF -+ CHz=CHF + H F have been studied in a static system over the temperature range 734-820'K. was shown to be first order and homogeneous, with a rate constant of The reaction log kz(s-l) = 13.39 f 0.2 -(62.9 f 0.9)/0 wher