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Anomalous double minima in the angular variation of endor transitions

✍ Scribed by Charles A. McDowell; Devulapalli L. Sastry


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
525 KB
Volume
198
Category
Article
ISSN
0022-2860

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The roto-torsional energy levels of HSSH and DSSD up to J Ο­ 20 are evaluated variationally with a Hamiltonian expressed in terms of internal coordinates. The kinetic and potential parameters are derived from ab initio calculations with full optimization of the geometry. The calculated levels are emp